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Absolute Rate Constants for the Reactions of Cl Atoms with CH 3 Br, CH 2 Br 2 , and CHBr 3

✍ Scribed by Kambanis, Kyriakos G.; Lazarou, Yannis G.; Papagiannakopoulos, Panos


Book ID
127036564
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
143 KB
Volume
101
Category
Article
ISSN
1089-5639

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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m

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## Abstract Rate coefficients for the reactions of CH~3~ + Br~2~ (__k__~2~), CH~3~CO + Br~2~ (__k__~3~), and Cl + Br~2~ (__k__~5~) were measured using the laser‐pulsed photolysis method combined with detection of the product Br atoms using resonance fluorescence. For the reactions involving organic