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Temperature Dependence of the Rate Constants and Branching Ratios for the Reactions of Cl - (D 2 O) 1-3 with CH 3 Br and Thermal Dissociation Rates for Cl - (CH 3 Br)

✍ Scribed by Seeley, John V.; Morris, Robert A.; Viggiano, A. A.; Wang, Haobin; Hase, William L.

Book ID: 121403200
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 230 KB
Volume: 119
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja960872u

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## Abstract Rate coefficients for the reactions of CH~3~ + Br~2~ (__k__~2~), CH~3~CO + Br~2~ (__k__~3~), and Cl + Br~2~ (__k__~5~) were measured using the laser‐pulsed photolysis method combined with detection of the product Br atoms using resonance fluorescence. For the reactions involving organic