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Measurements of the kinetics of the OH-initiated oxidation of α-pinene: Radical propagation in the OH+α-pinene+O2+NO reaction system

✍ Scribed by Maxine E. Davis; Philip S. Stevens

Book ID
113475952
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
276 KB
Volume
39
Category
Article
ISSN
1352-2310

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## Abstract The mechanism of the OH‐initiated oxidation of β‐pinene in the presence of NO has been investigated using a discharge‐flow system at 5 Torr and 300 K. OH radical concentrations were measured as a function of reaction time by laser‐induced fluorescence (LIF). The rate constant for the OH

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## Abstract The rate constants for the OH + α‐pinene and OH + β‐pinene reactions have been measured in 5 Torr of He using discharge‐flow systems coupled with resonance fluorescence and laser‐induced fluorescence detection of the OH radical. At room temperature, the measured effective bimolecular ra