Theoretical Study of the Formation of Acetone in the OH-Initiated Atmospheric Oxidation of α-Pinene
✍ Scribed by Vereecken, L.; Peeters, J.
- Book ID
- 127003301
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 84 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The production of dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO~2~) in the dimethyl sulfide (DMS) degradation scheme initiated by the hydroxyl (OH) radical has been shown to be very sensitive to nitrogen oxides (NO~__x__~) levels. In the present work we have explored the potentia
## Abstract The mechanism of the OH‐initiated oxidation of β‐pinene in the presence of NO has been investigated using a discharge‐flow system at 5 Torr and 300 K. OH radical concentrations were measured as a function of reaction time by laser‐induced fluorescence (LIF). The rate constant for the OH