We examine the question of reduced Hamiltonians for the torsion-rotation problem and in particular the question of the continuity of frequencies obtained by projecting out a large-amplitude torsional coordinate. We find that suitable results for torsion-rotation analysis can be obtained using either
Measurements of [OH] and [CH3CHO] oscillations and phase relations in the combustion of CH3CHO
โ Scribed by Pugh, Spencer A.; Kim, Hyung-Rae; Ross, John
- Book ID
- 120222564
- Publisher
- American Institute of Physics
- Year
- 1987
- Tongue
- English
- Weight
- 871 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.452280
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Using a pulse-radiolysis transient UV-VIS absorption system, rate constants for the reactions of F atoms with CH 3 CHO (1) and CH 3 CO radicals with O 2 (2) and NO (3) at 295 K and 1000 mbar total pressure of SF 6 was determined to be By monitoring the for-ฯช12 ฯช11 3 ฯช1 ฯช1 (4.4 ฯฎ 0.7) ฯซ 10 , and k ฯญ
This paper concerns itself primarily with three questions: (i) What is the range of commonly used definitions for the internal rotation angle, and how do variations within this range affect intercomparisons among results from various laboratories? (ii) Do the force-constant and projected-frequency v