Gaseous ion mobility data are used to test theorcticai potentials for H?j + He at large separation distances. Agreement with ab initio calculations is good, but significant discrepancy with recent dhtomics-m-molecules calculations is found. Mobility data are also used to calculate the spherically-av
Measurements of absolute integral total cross sections of He—H2 and the interaction potential
✍ Scribed by R. Gengenbach; Ch. Hahn
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 321 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The integral total collision cross section for tie H 2 has been measured with an absolute accuracy of -+ 1% to -+4% between 0.14 meV and 2.9 eV. The data have been fitted by a spherical symmetric multiparameter Morse-splinedispersion potential, which agrees well with results of ab initio calculations at short distances. The long range attraction can be described by the theoretical van der Waals constant C 6, if the dipole-quadrupole interaction -Cs R -a with C 8 = 41 au is taken into account. The potential has one bound state for every possible isotopic combination.
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