## Abstract NMR relaxation parameters are usually derived from series of 2D experiments. The whole procedure can be very time consuming, especially for the study of the relaxation of nuclei at natural abundance. Palmer and Mandel have proposed the use of accordion spectroscopy to determine one rela
Measurement of Relaxation-Rate Constants Using Constant-Time Accordion NMR Spectroscopy
β Scribed by A.M. Mandel; A.G. Palmer
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 939 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1064-1858
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
An experimental approach for the measurement of nuclear magnetic spin relaxation rate constants that combines triple-resonance techniques and accordion spectroscopy is described. Pulse sequences are discussed for the measurement of backbone 15N and 13CO R1 relaxation rate constants. The three-dimens
The technique of multiple-quantum J-resolved NMR spectroscopy (MQ-JRES) is introduced and applied to the spin system SI 3 -M (such as in the example given here, the 13 CH 3 -12 CH in alanine). The SI 3 spin system was excited to its highest quantum state (8S y I x I y I y ), which consists of four c
A recent analysis of the optimization of magnetization transfer experiments to estimate first-order rate constants is extended to the design of experiments for measuring these constants and T , when both parameters are initially unknown. When the number of measurement times is fixed, an optimal desi