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Mass spectrometry of the silver nitrate derivatives of cyclopropenoid compounds

✍ Scribed by T.A. Eisele; L.M. Libbey; N.E. Pawlowski; J.E. Nixon; R.O. Sinnhuber

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
367 KB
Volume
12
Category
Article
ISSN
0009-3084

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✦ Synopsis

dihexylcyclopropene, 1,2-diheptylcyclopropene, 1,2-dioctyleyclopropene, methyl malvalate, and methyl sterculate have been reacted with silver nitrate in methanol to form the corresponding methoxy and ketone derivatives. GLC, IR, and MS data are presented. The mass spectra and a possible method for determining the cyclopropene ring position are discussed.

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