Mass spectrometry of the trimethylsilyl derivatives of medicinal barbiturates
β Scribed by Fred C. Falkner; J. Throck watson
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 519 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1076-5174
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Recent trends towards increasing abuse of the barbiturates has led to a proposal to legally restrict some of them. The implementation of the resulting legislation might require specific identification of the barbiturates. Such identification is not readily available from electron impact mass spectra
## Methoxime-trimethylsilyl derivatives of prostaglandin A, B, and E series and trimethylsilyl derivatives of prostaglandin F series were investigated by gas chromatography-chemical ionization (CI) mass spectrometry. In ammonia CI mass spectrometry of both derivatives, the ion at m/e (M + l)+ or (