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Mass Spectrometry of o-Ethyl-o-Aryl-Phenylphosphonothioates

✍ Scribed by W. Steurbaut; W. Dejonckheere; N. De Kimpe; L. Schreyen

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
220 KB
Volume
86
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

The mass spectra of O‐ethyl‐O‐aryl‐phenylphosphonothioates are investigated and discussed. Besides direct classical fragmentation (α‐fissions), migration of both an aryl group and a double bond occurs between sulphur and oxygen prior to fragmentation, resulting in some unexpected m/e valvues. The most abundant ion was m/e 157, which could be reasonably explained in terms of loss of a phenoxy moiety followed by ethylene expulsion.

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