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Mass Spectra of Amides of 2-Amino-2-thiazoline

✍ Scribed by Marie-Pierre Viallet; Jacques Ulrich; André Boucherle

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
331 KB
Volume
313
Category
Article
ISSN
0365-6233

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✦ Synopsis

Abstract

Five fragmentation patterns of the molecular ions of sixteen amides of 2‐amino‐2‐thiazoline and of one deuteriophenyl derivative are described: when R is a phenyl group substituted in ortho position by an R″ group, the [M‐R″]^+^ ion is the main fragment, whereas in the other cases R″ = substituent in meta or para position it is the ion [M‐H]^+^. The amino⇄imino tautomerism of these molecular ions was studied. In addition, a correlation was found between the fragmentation patterns of the molecules and their pharmacological activities.

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