✦ LIBER ✦

The Mass Spectra of 2-Substituted Permethylated Trisilanes

✍ Scribed by Taewook Kim; Chang Hwan Kim; Myong Euy Lee

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 211 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(199605)10:7<767::aid-rcm552>3.0.co;2-4

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✦ Synopsis

Mass spectra of ten %substituted permethylated trisilanes which include compounds with halo, phenyl and hydrido substituents are reported. Labelling with a C03 group disclosed that a terminal silicon is more favourable as a charge position for the trisilyl cation than the middle atom and that a-and &elimination of two groups on a silicon atom takes place competitively.

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