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Magnitudes of Arrhenius parameters for decomposition reactions of solids

✍ Scribed by Andrew K. Galwey

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
326 KB
Volume
242
Category
Article
ISSN
0040-6031

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Arrhenius parameters for the alkoxy radi
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✍ Kwang Yul Choo; Sidney W. Benson πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 558 KB

## Abstract Arrhenius parameters for the decomposition reactions of various alkoxy radicals are evaluated. The recommended values for __tert__‐butoxy radical decomposition reaction are log __A__ (s^βˆ’1^) = 14.1, __E__~__a__~ = 15.3 kcal/mol. magnified image The parameters give reasonably self‐consis

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The preceding paper describes the reanalysis by Kerr and Parsonage (following discussions with one of us, H.W.S.) of some of our published work. We are grateful to Dr. Kerr for communicating their conclusions to us. We agree in principle with their analysis, and the present communication is to repor

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✍ L. Batt; G. N. Robinson πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 146 KB πŸ‘ 1 views

The recent paper of Choo and Benson [l] prompted us to communicate our most recent results for the gas-phase decomposition of the t-butoxy radical. The method we have used was to decompose ditertiary butyl peroxide (-10-5M) in the presence of nitric oxide (-10-5M) and inert gas (25-1500 torr) in a s

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✍ D. S. Jones; S. J. Moss πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 428 KB πŸ‘ 1 views

Competitive studies of the reactions of ground-state oxygen atoms, generated by mercury-photosensitized decomposition of nitrous oxide, have been carried out with ethylene and all the fluoroethylenes using 2-(trifluoromethy1)-propene as reference compound. From measurements at 25Β°C and 150Β°C relativ