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MAGNETIC INVESTIGATIONS OF SPIN-FREE COBALTOUS COMPLEXES. IV. MAGNETIC PROPERTIES AND SPECTRUM OF COBALT(II) ORTHOSILICATE

โœ Scribed by Goodgame, Margaret; Cotton, F. Albert

Book ID
121452551
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
243 KB
Volume
65
Category
Article
ISSN
0022-3654

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โœ Kouichi Fukui; Hiroaki Ohya-Nishiguchi; Noboru Hirota; Katsuhiro Aoyagi; Hisanob ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 435 KB

It is shown by EPR and magnetic susceptibility (x) measurements that acetate-N-methyl-octaethylporphyrinato-Co(I1) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and x with kn= 4.4 BM and Dz 20 cm-', which indicates square-pyramidal geometry around Co( II