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Magnetic and optical properties of low-spin cobalt(II) complexes

โœ Scribed by Yuzo Nishida; Sigeo Kida

Book ID
107768579
Publisher
Elsevier Science
Year
1971
Weight
114 KB
Volume
7
Category
Article
ISSN
0020-1650

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โœ Kouichi Fukui; Hiroaki Ohya-Nishiguchi; Noboru Hirota; Katsuhiro Aoyagi; Hisanob ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 435 KB

It is shown by EPR and magnetic susceptibility (x) measurements that acetate-N-methyl-octaethylporphyrinato-Co(I1) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and x with kn= 4.4 BM and Dz 20 cm-', which indicates square-pyramidal geometry around Co( II