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Magnetic Investigations of Spin-free Cobaltous Complexes. V. Tetra-azido and Tetracyanato Cobaltate(II) Ions

✍ Scribed by Cotton, F. Albert; Goodgame, Margaret


Book ID
120618063
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
474 KB
Volume
83
Category
Article
ISSN
0002-7863

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The tetra(4-t-butyl)phthalocyanine derivatives of Co and Cu have been studied by ESR spectroscopy in solution owing to their solubility in polar and non-polar solvents. The cobalt complex gives a well-resolved EPR spectrum in toluene glass at 77 K with g k = 2.018, g c = 2.785, A k = 0.0155 cm Γ€1 ,