Fluorescence polarization of pyrimidine in a supersonic jet has been examined in the absence of an external field with excitation at each of the rotational lines of the various vibronic absorption bands belonging to the S&i transitions. The internal magnetic field which depolarizes the fluorescence
Magnetic field effects on the fluorescence polarization of pyrimidine in a supersonic jet
โ Scribed by Nobuhiro Ohta; Masahisa Fujita; Hiroaki Baba
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 422 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Polarization of the fluorescence of pyrimidine in a supersonic jet, and external magnetic field effects thereupon have been observed with excitation at individual rovibronic absorption lines belonging to the O-O band of the So-S, transition. On excitation at the R( 0) line, the decays of the parallel and perpendicularly polarized fluorescence exhibit Zeeman quantum beats which are out of phase with each other. Fluorescence depolarization induced by an "internal" magnetic field IS aIso observed.
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