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Internal magnetic field effects on fluorescence polarization at s1 vibronic levels of pyrimidine in a supersonic jet

✍ Scribed by Nobuhiro Ohta; Hiroaki Baba

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 445 KB
Volume: 146
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87468-2

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✦ Synopsis

Fluorescence polarization of pyrimidine in a supersonic jet has been examined in the absence of an external field with excitation at each of the rotational lines of the various vibronic absorption bands belonging to the S&i transitions. The internal magnetic field which depolarizes the fluorescence acts on the slow component of the fluorescence, but not on the fast component.

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Magnetic field effects on the fluorescence polarization of pyrimidine in a supersonic jet

✍ Nobuhiro Ohta; Masahisa Fujita; Hiroaki Baba 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 422 KB

Polarization of the fluorescence of pyrimidine in a supersonic jet, and external magnetic field effects thereupon have been observed with excitation at individual rovibronic absorption lines belonging to the O-O band of the So-S, transition. On excitation at the R( 0) line, the decays of the paralle