Magnetic circular dichroism studies. XVI. Magnetic circular dichroism investigations of some conjugated olefins
β Scribed by Dauben, William G.; Seeman, Jeffrey I.; Wendschuh, Peter H.; Barth, Guenter.; Bunnenberg, Edward.; Djerassi, Carl.
- Book ID
- 126111271
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 523 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-3263
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T h c magnetic circular dichroism spectra of a numbcr of indolc alkaloids show two B-tcrms of opposite sign in thc 250-330 nni wavelength region associated with the l L b and lL, clectronic transitions, thc long ivavelength, lLt,, band being of positive sign, whereas both bands strongly ovcrlap in a
The MCD spectra of hexachlorobemede, 1,3,5-t~ichlorobenzene, hexabromobenzene and 1,3,5-triiromobenzene have been measured. For each molecule, the Faraday A term was observed in the region of the \*At& 'Etu transition and thereby the magnetic moment in the \*E tu state was extracted. It appears that