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Magnetic circular dichroism studies. XVI. Magnetic circular dichroism investigations of some conjugated olefins

✍ Scribed by Dauben, William G.; Seeman, Jeffrey I.; Wendschuh, Peter H.; Barth, Guenter.; Bunnenberg, Edward.; Djerassi, Carl.


Book ID
126111271
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
523 KB
Volume
37
Category
Article
ISSN
0022-3263

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T h c magnetic circular dichroism spectra of a numbcr of indolc alkaloids show two B-tcrms of opposite sign in thc 250-330 nni wavelength region associated with the l L b and lL, clectronic transitions, thc long ivavelength, lLt,, band being of positive sign, whereas both bands strongly ovcrlap in a

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The MCD spectra of hexachlorobemede, 1,3,5-t~ichlorobenzene, hexabromobenzene and 1,3,5-triiromobenzene have been measured. For each molecule, the Faraday A term was observed in the region of the \*At& 'Etu transition and thereby the magnetic moment in the \*E tu state was extracted. It appears that