Magnetic circular dichroism of manganese pentacarbonyl bromide

✍ Scribed by R.M.E. Vliek; P.J. Zandstra

• Book ID: 103014791
• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 496 KB
• Volume: 31
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85069-x

✦ Synopsis

The nbsar&n and magnetic circular dichroism (MCD) spectra of manganese pentacarbonyi bromide hfn(CO)SBr in a soIution of 2-methyl tetrahydrofuran Were measured at various temperatures over the 550045@0 A regon. wititi cx~ti mental error the MCD spectra rue not temperature dependent and in addition to a negatieB term exhldit a positiveA term, in.icative for a degenerate excited state. Following the kreducib!e tensor method we con&de that the transition involved will be mainly e[n, Br] -+ al [u closely with the expe&ental value. *, 3d,z] and for the excitrd state we calculate a magnetic moment which agrees quite l.Introduction ', '..