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Magnetic Circular Dichroism and Absorption Spectra of 2-Methyl-1, 3-diazaazulene

✍ Scribed by Hiroyuki Yamaguchi; Masafumi Ata; Koichi Toyoda; Hiroaki Mametsuka; Hitoshi Takeshita; Harold Baumann

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
262 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The magnetic circular dichroism and UV. spectra of 2‐methyl‐1, 3‐diazaazulene (2) have been measured. The UV. spectrum is interpreted by making use of CNDO/S MO CI calculations. Our assignment of the first and second absorption band coincides with one of the corresponding bands of 1, 3‐diazaazulene (1) given by Small & Burke. The third and fourth absorption bands are in agreement with those published by Hiratsuka et al. and Tanizaki et al. for 1 and 2‐ethoxy‐1, 3‐diazaazulene, respectively.

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