The rate of nitration of chlorobenzene in 70.2 per cent sulphuric acid has been determined in the two phase system and also in each phase separately. Data on the solubility of chlorobenzene in the acid phase has also been obtained. The rate of nitration in the organic phase is negligible while that
Macrokinetics of chlorobenzene nitration
โ Scribed by C. Hanson; J.G. Marsland; M.A. Naz
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 389 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-2509
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โฆ Synopsis
NOTE ADDED IN PROOF
Note that when calculatmg 8' and g* accordmg to Eq (1 I), we need not know y(s) exphcltly, only its 1st and 2nd denvatlves for s = 0 However, these denvatlves can be obtamed directly from Eq (9), namely by lmphclt dlfferentlatlon and by substltutmg s = 0 finally In this way, an algorithm has now been given to determme 8 and g* even m the most general case of the process called "multlphase chromatography" m this article
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