## Abstract The reaction of fluorescamine with 6‐aminopenicillanic acid (6‐APA) at pH 4 was investigated for its potential use in the biosynthesis of benzylpenicillin. A number of amino acids and penicillin amine derivatives, that reacted with fluorescamine at pH 7–9, were unlikely to do so to a si
✦ LIBER ✦
Macrocylic Amines — Precursors to some colorful chemistry
✍ Scribed by O.D. Gupta; Robert L. Kirchmeier; Jeańne M. Shreeve
- Book ID
- 104150292
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 26 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
✦ Synopsis
The interactions of macrocyclic amines with cyclic polyfluorinated olefins provide a route to a rather large new family of one, two, three or four substituted derivatives that are stable to hydrolysis and that have surprising thermal properties.
Additionally, these materials are precursors to metal and nonmetal compounds, some of which are highly colored and which show an interesting chemistry in their own right. X-ray crystal structures are most useful in confirming these new macrocycles.
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