M2As2O7(H2O)2(M = Co or Ni): hydrous diarsenates with an intersecting tunnel structure
β Scribed by Wang, Sue-Lein; Horng, Jia-Cherng; Lee, Yan-Huang
- Book ID
- 118261002
- Publisher
- The Royal Society of Chemistry
- Year
- 1994
- Tongue
- English
- Weight
- 740 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1472-7773
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The crystal structure determination of the title compounds showed that they are isomorphous, revealing the general formula [M(H,O),(py)z](sac),. 4H,O. Their structures are built up of [M(H,0),(py)z]2' cations, saccharinato anions and non-coordinated water molecules. The metal atom lies on the invers
A novel lead vanadophosphate, PbVOP 2 O 7 , has been synthesized. This phase crystallizes in the Pnma space group with a β«)1(998.8Ψβ¬ A > , b β«Ψβ¬ 7.534(1) A > , and chains running along b l , interconnected through P 2 O 7 groups forming large intersecting tunnels running along b l , al , and cl , r