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A novel Mo(V) diphosphate with an intersecting tunnel structure: Sr(MoO)2(P2O7)2

✍ Scribed by Anne Guesdon; Bernard Raveau


Book ID
114370244
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
348 KB
Volume
2
Category
Article
ISSN
1293-2558

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A new molybdenum ( \(\mathrm{V}\) ) monophosphate \(\mathrm{K}_{2} \mathrm{Mo}_{2} \mathrm{P}_{2} \mathrm{O}_{11}\) has been isolated. The single crystal \(\mathrm{X}\)-ray diffraction study of this phase has shown that it is isotypic with \(\mathrm{K}_{2} \mathrm{Nb}_{2} \mathrm{As}_{2} \mathrm{O}_

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A novel lead vanadophosphate, PbVOP 2 O 7 , has been synthesized. This phase crystallizes in the Pnma space group with a ‫)1(998.8؍‬ A > , b ‫؍‬ 7.534(1) A > , and chains running along b l , interconnected through P 2 O 7 groups forming large intersecting tunnels running along b l , al , and cl , r