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Two novel Mo(V) and Mo(V)/Mo(VI) barium phosphates with a tunnel structure: β-Ba(MoO)2(P2O7)2, and Ba(MoO)2O(P2O7)PO4

✍ Scribed by André Leclaire; Valérie Pralong; Bernard Raveau

Book ID
108195241
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
605 KB
Volume
178
Category
Article
ISSN
0022-4596

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Mo(V) Phosphates with an Opened Framework: Li4−xA+x(MoO)3(PO4)3P2O7(A=Na, Ag, Cs, K), Li4−xBa2+x/2(MoO)3(PO4)3P2O7
✍ S. Ledain; A. Leclaire; M.M. Borel; M. Hervieu; J. Provost; B. Raveau 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 514 KB

The exploration of Li+A+Mo+P+O systems has allowed several Mo(V) phosphates, Li 4؊x A x (MoO) 3 (PO 4 ) 3 P 2 O 7 (A ‫؍‬ Na, Ag, Cs, K) and Li 3 Ba 0.5 (MoO) 3 (PO 4 ) 3 P 2 O 7 , to be synthesized. Two types of closely related structures are evidenced depending on the nature and content of the A ca