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Lysilactones A–C, three 6H-dibenzo[b,d]pyran-6-one glycosides from Lysimachia clethroides, total synthesis of Lysilactone A

✍ Scribed by Liang, Dong; Luo, Huan; Liu, Yan-Fei; Hao, Zhi-You; Wang, Yan; Zhang, Chun-Lei; Zhang, Qing-Jian; Chen, Ruo-Yun; Yu, De-Quan


Book ID
120620082
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
381 KB
Volume
69
Category
Article
ISSN
0040-4020

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A one-pot synthesis of 8-amino-1-methoxy
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## Abstract 8-Amino-1-methoxy-6H-dibenzo[b,d]pyran-6-one was synthesized in a one-pot reaction of 2′,6′-dimethoxy-4-nitro-1,1′-biphenyl-2-carboxylic acid methyl ester using hydroiodic acid as a reagent to effect O-demethylation, lactonization, and nitro reduction to amine. This new reaction represe