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Low-Valent Niobium-Catalyzed Reduction of α,α,α-Trifluorotoluenes.

✍ Scribed by Kohei Fuchibe; Yoshitaka Ohshima; Ken Mitomi; Takahiko Akiyama


Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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Abstract

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ChemInform Abstract: Low-Valent Titanium
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Low-Valent Titanium Induced Novel Reductive Cyclizations of α,β-Unsaturated Nitrile Compounds. -Cyclopentenes such as (II), (IV), and (VII) are easily prepared by cyclodimerization of α,β-unsaturated nitriles promoted by low-valent titanium reagent. Using the same reagent for nitro-compounds such a