Hydrogenation of the Carbonyl Group in α-Ketoesters and α-Ketoamides Catalyzed by Ruthenium Clay. -The ruthenium clay, prepared from montmorillonite K10, (3-chloropropyl)trimethoxysilane, KPPh 2 , and RuCl 3 •H 2 O (0.13 to 0.17 mmol Ru/g clay) catalyzes effectively the reduction of the α-carbonyl
ChemInform Abstract: Ruthenium Clay Catalyzed Reduction of α-Iminoesters and α-Iminoketones, and the Reductive Amination of α-Ketoesters.
✍ Scribed by Raluca Aldea; Howard Alper
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 40 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Diastereomeric reduction of nonactivated, hindered β‐keto and chiral β‐iminoesters are described. The influence of a α‐stereocontrolled center on the efficiency and stereoselectivity of the reduction was studied. Reaction conditions were optimized to synthesize β‐hydroxy‐ and β‐aminoest
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v