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ChemInform Abstract: Hydrogenation of the Carbonyl Group in α-Ketoesters and α-Ketoamides Catalyzed by Ruthenium Clay.

✍ Scribed by Raluca Aldea; Howard Alper

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199923069

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✦ Synopsis

Hydrogenation of the Carbonyl Group in α-Ketoesters and α-Ketoamides Catalyzed by Ruthenium Clay.

-The ruthenium clay, prepared from montmorillonite K10, (3-chloropropyl)trimethoxysilane, KPPh 2 , and RuCl 3 •H 2 O (0.13 to 0.17 mmol Ru/g clay) catalyzes effectively the reduction of the α-carbonyl group of ketoesters and ketoamides to give the corresponding hydroxyesters and -amides in 80-89% isolated yields. -

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