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Low-temperature Mössbauer measurement of a polymeric oxalate (2,2′-bipyridine) iron compound

✍ Scribed by Krause, M. ;Michalk, C. ;Benedix, M. ;Suwalski, J.

Book ID
105378584
Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
232 KB
Volume
90
Category
Article
ISSN
0031-8965

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The trigonal planar high-spin ferric compound, Fe[N(SiMe a 2 a, exhibits a very large temperature-independent 1 I quadrapole splitting & e2 Qq = 6.12 mm see-') in its 57Fe Miissbauer spectrum between I.5 and 300°K. At low temperatures a novel type of magnetic hyperfme spectrum is observed. The (fluc