Low-energy electron attachment to SF[sub 6]. I. Kinetic modeling of nondissociative attachment
✍ Scribed by Troe, Jürgen; Miller, Thomas M.; Viggiano, Albert A.
- Book ID
- 118749722
- Publisher
- American Institute of Physics
- Year
- 2007
- Tongue
- English
- Weight
- 788 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0021-9606
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📜 SIMILAR VOLUMES
Thermochemical analysis of the electron capture process of SFs leads to a rate constant for the reverse process SF; 2 SF6 + e-, k 2 = 1.5 X 1013-31'.4/H s-l, where 0 = 2.303RT, in kcal/mol. The electron affinity of 32 f 3 kcal/mol is deduced from the observed bimolecularity of the capture process do
EkCt~on attachment to SF6 hss been Stidicd at low prcs;urc in the 8s phk by ion cyclotron resomnce (ICR) spec-'tioscopy. Formation of stable SF; tinder cbllision-free conditions is rationdzed on the basis of radiative relaxaticn by (SF;!\*. The utility of ICR for inve$gatin~ electron attaclment at e