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Low-energy electron attachment to C6F5X (X=F, Cl, Br and I)

✍ Scribed by Hiroshi Shimamori; Takeyoshi Sunagawa; Yuji Ogawa; Yoshitsugu Tatsumi

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 723 KB
Volume: 227
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00867-1

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The kinetics of the thermal bromination reaction ( 3 ) have been studied in the range of 26lo-391"C. The observed rate law is compatible with initiation by the step (6) for which we obtain Brz + CsFsI -BrI + C6FsBr Br + C6FJ -BrI + C6F5 log k6(cm3/mol. sec) = (13.41 f 0.26) -(11700 f 700)/6 where 8