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Bissilylierte Haloniumionen: [Me3SiXSiMe3][B(C6F5)4] (X=F, Cl, Br, I)

✍ Scribed by Mathias Lehmann; Axel Schulz; Alexander Villinger

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 360 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200902992

No coin nor oath required. For personal study only.

✦ Synopsis

Ionen des Typs [R À X À R] + mit X = Halogen werden als Haloniumionen bezeichnet. Sie treten sowohl cyclisch als auch offenkettig auf, bilden eine bedeutende Klasse von Oniumionen [1, 2] und spielen eine wichtige Rolle in der präparativen Chemie, z. B. als Zwischenstufen bei Friedel-Crafts-Alkylie

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