Localized ckcrrons XII irradiated l,~he~~~ol and l&octar&iol have been identified and studied by E.SR spectroxopy at 4 K. The spectra show an an&tropic hyperfine sLruclure with eouplmgs less than 35 G due to at least IWO protons Spccua recorded from crystals with deuteraled hydroxyl groups vmfy that
Localized electrons in 1,8-octanediol crystals studied by ESR spectroscopy and pulse radiolysis
โ Scribed by P.-O. Samskog; A. Lund; G. Nilsson
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 357 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Localized electrons in 1 .d~ctanediol crystals have been studled by pulse radlolysls and ESR spectroscopy. The maximum of the optxal absorption LS at 625 nm The decay E first order with an actwation energy of 16 3 kJ mole-'. The assgnment of the optxal spectrum his been made by ESR at 67 K When the electron decays the -CH2tHCHz-radxaJ grows In Volume 79, number 3 CHEMICAL PHYSKS LETTERS
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