Local modes of silane within the framework of stretching vibrational polyads
✍ Scribed by H. Crogman; V. Boudon; D. A. Sadovskií
- Book ID
- 111628228
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 385 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1434-6060
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📜 SIMILAR VOLUMES
The (3000) and ( ) stretching overtone bands of silane, SiH.,, have been observed near 6362 and IO268 cm-' by Fourier transfer spectroscopy with a resolution of 0.01 cm-'. In both spectra the pseudo-symmetric-top rotational structure, similar to that observed in the (3000) band of germane, was clear
The stretching and bending vibrations of methane are described in a local-mode anharmonic symmetry adapted model. Both Hecht-and Fermi-like interactions are considered. We start by establishing the Hamiltonian of the system in terms of internal coordinates and momenta. The Hamiltonian is then rewrit