Living radical polymerization in homogeneous system with phenylazotriphenylmethane as a thermal iniferter
β Scribed by Takayuki Otsu; Toshiniri Tazaki
- Book ID
- 104685222
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 424 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
The bulk polymerization of methyl methacrylate (MMA) initiated with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS) was studied. This polymerization showed some "living" characteristics; that is, both the yield and the molecular weight of the resulting polymers increased with reaction time, and th
radical polymerizations of styrene, methyl methacrylate, methyl acrylate, vinyl acetate, acrylonitrile and methacrylonitrile were carried out in the presence of photoiniferters (RDC) bearing an N,N-diethyldithiocarbamate group. The effects of the structure of RDC on the polymerizations were investig