The bulk polymerization of methyl methacrylate (MMA) initiated with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS) was studied. This polymerization showed some "living" characteristics; that is, both the yield and the molecular weight of the resulting polymers increased with reaction time, and th
Radical polymerization of methyl methacrylate with methyl 2,2-dimethyl-3,3-diphenyl-3-cyanopropionate as a thermal iniferter
β Scribed by Toshinori Tazaki; Takayuki Otsu
- Publisher
- Springer
- Year
- 1987
- Tongue
- English
- Weight
- 318 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
The title compound, the first member of a homologous series of oligomers formed by free radical polymerization of methyl methacrylate initiated by tetraphenylbutanedinitrile, was synthesized and its structure was determined by X-ray diffraction. The longest C--C bond of this molecule measures 1.628
Two new monomers based on thioxanthone, 2-(3@-acryloxy)propoxythioxanthone (M-2) and 1-methyl-4-(3@-acryloxy)propoxythioxanthone (M-4), were prepared and their radical copolymerization at 70Β‘C with methyl methacrylate (MMA) was studied. By varying the conversion reached for a Γxed feed composition,