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Features of living radical polymerization of vinyl monomers in homogeneous system using N,N-diethyldithiocarbamate derivatives as photoiniferters

✍ Scribed by Takayuki Otsu; Toshiaki Matsunaga; Toru Doi; Akikazu Matsumoto

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 1000 KB
Volume: 31
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(94)00122-7

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✦ Synopsis

radical polymerizations of styrene, methyl methacrylate, methyl acrylate, vinyl acetate, acrylonitrile and methacrylonitrile were carried out in the presence of photoiniferters (RDC) bearing an N,N-diethyldithiocarbamate group. The effects of the structure of RDC on the polymerizations were investigated as well as the effects of the conditions such as the monomer and iniferter concentrations, the polymerizati'on temperature and the wavelength of the irradiation light. The appropriate conditions for the living radical polymerizations of these monomers were determined. Stabilization of the iniferter site at the chain end was also attempted.

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