## Abstract The bulk free‐radical polymerization of styrene in the presence of a new cyclic trifunctional initiator, 3,6,9‐triethyl‐3,6,9‐trimethyl‐1,4,7‐triperoxonane, was studied. Full‐conversion‐range experiments were carried out to assess the effects of the temperature and initiator concentrati
Living free radical polymerization using cyclic trifunctional initiator
✍ Scribed by Eduardo Galhardo; Paula Magalhães Bonassi Machado; Liliane Maria Ferrareso Lona
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 920 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0021-8995
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&&Living'' free-radical polymerization (LFRP) of styrene is usually performed following two di!erent reaction procedures: by TEMPO-mediated LFRP or by atom transfer radical polymerization. The main di!erence between the previous two processes is related to how the exchange between the active and the
## Abstract Microgels which are soluble crosslinked polymer networks have been prepared using the nitroxide living free radical polymerization methodology. When heated in the presence of __tert__‐butylstyrene and 1,4‐divinylbenzene, the alkoxyamine 1 derived from 2,2′‐azoisobutyronitrile (AIBN) aff
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