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Lithiation of 3,3‘-Dimethyl-2,2‘-bipyridine and Its Trimethylsilylated Compounds: X-ray Crystal Structure of [{2-CH(SiMe 3 )C 5 H 3 N} 2 {Li(tmeda)} 2 ] (tmeda = N , N , N ‘, N ‘-Tetramethylethylenediamine)

✍ Scribed by Leung, Wing-Por; Poon, Kathleen S. M.; Mak, Thomas C. W.; Zhang, Ze-Ying


Book ID
126249426
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
271 KB
Volume
15
Category
Article
ISSN
0276-7333

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## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b