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Synthesis and Structures of Solvent-Separated Lithium Zincates of the Type [Li(tmeda) 2 ] + [Me 3- n Zn{CH(SiMe 3 )Ph} n ] - ( n = 1−3, tmeda = 1,2-Bis(dimethylamino)ethane)

✍ Scribed by Westerhausen, Matthias; Wieneke, Michael; Ponikwar, Werner; Nöth, Heinrich; Schwarz, Wolfgang


Book ID
125893537
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
137 KB
Volume
17
Category
Article
ISSN
0276-7333

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✍ Westerhausen, Matthias ;Wieneke, Michael ;Rademacher, Bernd B. ;Schwarz, Wolfgan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 772 KB

## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b