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Synthesis of [LiPPh(SiMe3)(tmeda)]2 (from Mg(PHPh)2(tmeda) or Li(PHPh)(tmeda)) and the X-ray structure of the trans-isomer (tmeda = N,N,N′,N′-tetramethylethylenediamine)

✍ Scribed by Evamarie Hey; Colin L. Raston; Brian W. Skelton; Allan H. White


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
589 KB
Volume
362
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES


Synthesis and Characterization of Substi
✍ Westerhausen, Matthias ;Wieneke, Michael ;Rademacher, Bernd B. ;Schwarz, Wolfgan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 772 KB

## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b