✦ LIBER ✦

Liquid phase hydrogen abstraction from asymmetrically chlorinated ethanes by chlorine atoms

✍ Scribed by G. J. Martens; M. Godfroid; J. Verbeyst

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 380 KB
Volume: 81
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19720810104

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Liquid-phase hydrogen abstraction from c

Liquid-phase hydrogen abstraction from chlorinated ethanes by chlorine atoms

✍ G. J. Martens; J. A. Franklin; M. Godfroid; M. Delvaux; J. Verbeyst 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB

## Abstract The hydrogen abstraction from the chlorinated ethanes by chlorine atoms has been investigated in the liquid phase. Rate constants relative to that for hydrogen abstraction from chloroform have been measured between 267° and 333°K using a competition technique. The results are compared w

Gas-phase hydrogen abstraction from asym

Gas-phase hydrogen abstraction from asymmetrically halogenated ethanes by chlorine atoms

✍ G. J. Martens; M. Godfroid; J. Delvaux; J. Verbeyst 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

## Abstract The hydrogen abstraction from asymmetrically fluorinated and chlorofluorinated ethanes by chlorine atoms has been investigated in the gas phase between 264 and 333°K using the competition method. Arrhenius parameters for the reaction on both sites of the molecules are discussed.

Abstraction of chlorine atoms from chlor

Abstraction of chlorine atoms from chloromethanes by the cyclohexyl radical

✍ M. G. Katz; A. Horowitz; L. A. Rajbenbach 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 560 KB

The kinetics of chlorine atom abstraction from the chloromethanes (CM)CC14, CHCl3, and CHBCl2 by radiolytically generated cyclohexyl radicals has been studied in the liquid phase by a competitive method. The halogen abstraction data have been put on an absolute basis by comparing the rates of the me

Abstraction of chlorine atoms from polyc

Abstraction of chlorine atoms from polychloroalkanes. II. Neighboring group effect on the rates of chlorine abstraction by cyclohexyl radicals

✍ M. G. Katz; L. A. Rajbenbach 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 486 KB

A(C2C14) kcal mole ## 9 . mole-'sec-'

Assessment of theoretical procedures for

Assessment of theoretical procedures for hydrogen-atom abstraction by chlorine, and related reactions

✍ Bun Chan; Leo Radom 📂 Article 📅 2011 🏛 Springer 🌐 English ⚖ 246 KB

Kinetic isotope effect for hydrogen/deut

Kinetic isotope effect for hydrogen/deuterium abstraction by chlorine atoms from (CH3)2NNO2 and (CD3)2NNO2

✍ Yannis G. Lazarou; Panos Papagiannakopoulos 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 462 KB

The kinetic isotope effect for the abstraction of hydrogenideuterium from dimethylnitramine and dimethylnitramine-ds by chlorine atoms has been studied in the temperature range 273-353 K. The rate constant ratio k H / k D is given by the Arrhenius expression, k H / k o = (0.92 t-0.07)exp(286 ? 250/R