๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Gas-phase hydrogen abstraction from asymmetrically halogenated ethanes by chlorine atoms

โœ Scribed by G. J. Martens; M. Godfroid; J. Delvaux; J. Verbeyst


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
307 KB
Volume
8
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

โœฆ Synopsis


Abstract

The hydrogen abstraction from asymmetrically fluorinated and chlorofluorinated ethanes by chlorine atoms has been investigated in the gas phase between 264 and 333ยฐK using the competition method. Arrhenius parameters for the reaction on both sites of the molecules are discussed.


๐Ÿ“œ SIMILAR VOLUMES


Liquid-phase hydrogen abstraction from c
โœ G. J. Martens; J. A. Franklin; M. Godfroid; M. Delvaux; J. Verbeyst ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 254 KB

## Abstract The hydrogen abstraction from the chlorinated ethanes by chlorine atoms has been investigated in the liquid phase. Rate constants relative to that for hydrogen abstraction from chloroform have been measured between 267ยฐ and 333ยฐK using a competition technique. The results are compared w

Kinetic isotope effect for hydrogen/deut
โœ Yannis G. Lazarou; Panos Papagiannakopoulos ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 462 KB

The kinetic isotope effect for the abstraction of hydrogenideuterium from dimethylnitramine and dimethylnitramine-ds by chlorine atoms has been studied in the temperature range 273-353 K. The rate constant ratio k H / k D is given by the Arrhenius expression, k H / k o = (0.92 t-0.07)exp(286 ? 250/R

Hydrogen/deuterium abstraction by chlori
โœ J. Niedzielski; E. Tschuikow-Roux; T. Yano ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 543 KB

The abstraction of hydrogen/deuterium from CH3CH2C1, CH,CHDCl, and CH,CD,Cl by photochemically generated ground-state chlorine atoms has been investigated over the temperature range of 8-94ยฐC using methane as a competitor. Rate constant data for the following reactions have been obtained: (1) CH,C&C

Rate constants and kinetic isotope effec
โœ E. Tschuikow-Roux; F. Faraji; Jan Niedzielski ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 804 KB

The abstraction of hydrogen and deuterium from 1,2-dichIoroethane, 1,1,2trichloroethane, and two of their deuterated analogs by photochemically generated ground state chlorine atoms has been investigated in the temperature range 0-95ยฐC using methane as a competitor. Rate constants and their temperat