When a solid-liquid interface is intersected by a grain boundary, a grain-boundary groove forms at the interface. Experiments have been carried out using camphene (a transparent analogue of a metal in terms of solidification behaviour) which show that, if the grain boundary is not perpendicular to t
Liquid grooving at grain boundaries
β Scribed by B.S. Bokstein; L.M. Klinger; I.V. Apikhtina
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 323 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0921-5093
No coin nor oath required. For personal study only.
β¦ Synopsis
The kinetic dissolution and diffusion regimes of liquid grooving of grain boundaries with zero (or near-zero) dihedral angle at the top are discussed, and their perdominance criteria formulated. A new model of liquid grooving is proposed, according to which the top of the channel propagates in a diffusion regime, while its widening proceeds kinetically. Analytical (for the particular case of low solubility) and numerical solutions are obtained. The linear dimensions (depth and width) of the channel are estimated for the mixed regime.
π SIMILAR VOLUMES
AbstractΓThe unusual topographies of the grain boundary thermal grooves in Ni-rich NiAl were observed after annealing at 14008C. One of the surfaces forming the grain boundary groove exhibited no curvature measurable in the atomic force microscope, thus indicating its singular character. The theory
In the case of Fe-Ni-Cr alloys (without precipitation), we propose an electrochemical method which allows us to obtain a reproducible selective corrosion of grain boundaries (H,SO,-2N 25'C in the transpassive domain) . We establish a model of dissolution to explain the morphology of etched grooves .
Grain-boundary migration controls the growth and shrinkage of crystalline grains and is important in materials synthesis and processing. A grain boundary ending at a free surface forms a groove at the tip, which affects its migration. This coupled grooving and migration is studied for an initially s
This work studies the coupled grooving and migration of an initially straight, inclined grain boundary ending at a horizontal free surface with an inclination angle bΣΆ1. The coupled motion is separated into two time regimes. In Regime I, the grain boundary turns vertically at the groove root. In Reg