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Liquid chromatography–electrospray tandem mass spectrometry of dansylated polyamines and basic amino acids

✍ Scribed by Dr. Gottfried J. Feistner

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
510 KB
Volume
30
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Liquid chromatogrpahy‐electrospray tandem mass spectrometry allows identification of dansylated basic amino acids and polyamines with a high degree of specificity, including unambiguous acid and 2 hydroxycadaverine, and N^1^‐ and N^8^‐acetylspermidine. In favorable cases, characteristic fragmentation mechanisms permit identification even in the absence of authentic reference compounds. The method readily identified acetyldiaminopropane, citrul‐line, and diacetylspermine as metabolic products of Erwinia amylovora.

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