## Abstract Olive oil was converted into methyl esters which were autoxidized at 60 °C. The composition of oxidized products was determined by the comparison of infrared spectra and NMR spectra of the original and acetylated samples, the sample reduced with potassium iodide and the acetylated reduc
Lipid Oxidation. Part 4. Products of Thermooxidative Polymerization of Vegetable Oils
✍ Scribed by Pokorný, J. ;Kundu, M. K. ;Pokorný, S. ;Bleha, M. ;Čoupek, J.
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 422 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0027-769X
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✦ Synopsis
Abstract
The thermal treatment of vegetable oils was studied by gel chromatography on packings of styrene‐divinylbenzene copolymers. Unlike oils with a lower content of polyene acids, those with a high content of polyene acids contained a larger amount of higher oligomers of fatty acids. The gel chromatography of fatty acid methyl esters from heated oils allowed the determination of the ratio of intra‐ and intermolecular bonds arising by polymerization reactions. The results of determination of the iodine value of products were correlated with the data obtained by gel chromatography.
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