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Lipid Oxidation. Part 4. Products of Thermooxidative Polymerization of Vegetable Oils

✍ Scribed by Pokorný, J. ;Kundu, M. K. ;Pokorný, S. ;Bleha, M. ;Čoupek, J.


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
422 KB
Volume
20
Category
Article
ISSN
0027-769X

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✦ Synopsis


Abstract

The thermal treatment of vegetable oils was studied by gel chromatography on packings of styrene‐divinylbenzene copolymers. Unlike oils with a lower content of polyene acids, those with a high content of polyene acids contained a larger amount of higher oligomers of fatty acids. The gel chromatography of fatty acid methyl esters from heated oils allowed the determination of the ratio of intra‐ and intermolecular bonds arising by polymerization reactions. The results of determination of the iodine value of products were correlated with the data obtained by gel chromatography.


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