Lipase-catalyzed synthesis of monoacylglycerol in a homogeneous system
β Scribed by Julieta B. Monteiro; Maria G. Nascimento; Jorge L. Ninow
- Book ID
- 110430785
- Publisher
- Springer Netherlands
- Year
- 2003
- Tongue
- English
- Weight
- 64 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0141-5492
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The regioselective lipase-catalyzed acylation of isopropylidene glycerol using different vinyl esters as acyl donors in toluene was studied. Reaction progress and enantioselectivity were monitored by gas chromatography using a permethylated pcyclodextrin phase. All vinyl esters were completely conve
The direct, lipase-catalyzed esterifications of glycerol-3-phosphate in an organic solvent system and in a solvent free system were carried out. In a solvent free system only, LPA synthesis could be achieved within the acceptable reaction time. Open reaction system was preferable to closed reaction