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Lipase-Catalyzed Ring-Opening Copolymerization of ε-Caprolactone and β-Lactam

✍ Scribed by Stavila, E.; Alberda van Ekenstein, G. O. R.; Woortman, A. J. J.; Loos, K.

Book ID: 121445102
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 426 KB
Volume: 15
Category: Article
ISSN: 1525-7797
DOI: 10.1021/bm401514k

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a-Chloromethyl-a-methyl-b-propionolactone (CMMPL) has been copolymerized with e-caprolactone (CL) using a wide range of feed compositions and aluminium triisopropoxide [Al(O i Pr) 3 ] as an initiator. Random copolymers of CMMPL with CL were obtained. The pendant chloromethyl groups of the copolymer